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Carbon Sequestration

Carbon Sequestration is the process of removing carbon dioxide from the atmosphere and storing it in a terrestrial reservoir.  It is a geo-engineering approach to mitigate global warming since carbon is a greenhouse gas.  While carbon dioxide is naturally captured from the atmosphere through biological, chemical, and physical processes,  efforts to artificially influence carbon sequestration are currently underway.  Some management strategies to achieve carbon sequestration include the following: enhanced removal from agriculture (cover crops, no-till, soil building, restoration of degraded land, grazing management), iron fertilization of oceans to encourage the growth of phytoplankton, carbon capture from point sources of carbon pollution and geological storage in subterranean formations, chemical alteration to stable carbonate minerals, and reforestation.

Agriculture, Climate Change, and Carbon Sequestration
Carbon sequestration and reductions in greenhouse gas emissions can occur through a variety of agriculture practices. This publication provides an overview of the relationship between agriculture, climate change and carbon sequestration. It also investigates possible options for farmers and ranchers to have a positive impact on the changing climate and presents opportunities for becoming involved in the emerging carbon market.
FIND ARTICLE HERE

Soil Carbon Sequestration in Grazing Lands: Societal Benefits and Policy Implications
This manuscript examines the importance of grazing lands for sequestering soil organic carbon (SOC), providing societal benefits, and potential influences on them of emerging policies and legislation. Global estimates are that grazing lands occupy 3.6 billion ha and account for about one-fourth of potential carbon (C) sequestration in world soils. They remove the equivalent of 20% of the carbon dioxide (CO2) released annually into the earth's atmosphere from global deforestation and land-use changes. Atmospheric CO2 enters grazing lands soils through photosynthetic assimilation by green plants, subsequent cycling, and sequestration of some of that C as SOC to in turn contribute to the ability of grazing lands to provide societal (environmental and economic) benefits in every country where they exist. Environmental benefits provided include maintenance and well-being of immediate and surrounding soil and water resources, air quality, human and wildlife habitat, and aesthetics. Grazing lands contribute to the economic well-being of those living on the land, to trade, and to exchange of goods and services derived from them at local, regional, or national levels. Rates of SOC sequestration vary with climate, soil, and management; examples and conditions selected from US literature illustrate the SOC sequestration that might be achieved. Public efforts, policy considerations, and research in the United States illustrate possible alternatives that impact grazing lands. Discussion of US policy issues related to SOC sequestration and global climate change reflect the importance attached to these topics and of pending legislative initiatives in the United States. Addressing primarily US policy does not lessen the importance of such issues in other countries, but allows an in-depth analysis of legislation, US Department of Agriculture program efforts, soil C credits in greenhouse gas markets, and research needs.  FIND ARTICLE HERE

Carbon Sequestration Under Irrigated Switchgrass (Panicum virgatum L.) Production
Perennial herbaceous crops such as switchgrass are important sources of cellulosic biomass for the developing bioenergy industry. Assessments of how much C will be lost or sequestered into soil and the turnover rates of that C are needed to assist producers and policymakers in determining the long-term sustainability of biomass production. We used the natural 13C abundance of soils to calculate the quantity and turnover of C4–C inputs in irrigated fields cropped to switchgrass monocultures. Soil profile root biomass produced after three seasons averaged 3.9 Mg C ha−1 m−1. Five years of cropping showed a 1200 kg ha−1 increase in soil organic C (SOC) in the 0- to 15-cm depth increment, with no change below 15 cm. The surface 15 cm of soil cropped to ‘Kanlow’ and ‘Shawnee’ had a d13C enrichment of 3‰ above the native uncultivated soil, with 3.6‰ for ‘Cave in Rock,’ with an average 2‰ enrichment compared with the soil collected before switchgrass establishment. Enrichment in the 30- to 60- and 60- to 90-cm depths averaged 1.7 and 0.9‰, respectively. The amount of soil profile C4–C determined by d13C analysis showed a greater C input than determined by the difference in total C mass between the uncultivated native and cropped soils. The average accrual rate of C4–SOC was estimated at 1.0 Mg ha−1 yr−1. Estimates of the mean residence time of the C3–C under the irrigated C4 monocultures of switchgrass were >60 yr in the 0- to 15-cm and 30 to 55 yr in the 15- to 30-cm depth increments. On average, 24% of SOC in the 0- to 15-cm depth was derived from C4 cropping.  FIND ARTICLE HERE

Improving Estimates of Rangeland Carbon Sequestration Potential in the US Southwest
Rangelands make an important contribution to carbon dynamics of terrestrial ecosystems. We used a readily accessible interface (COMET VR) to a simulation model (CENTURY) to predict changes in soil carbon in response to management changes commonly associated with conservation programs. We also used a subroutine of the model to calculate an estimate of uncertainty of the model output based on the similarity between climate, soil, and management history inputs and those used previously to parameterize the model for common land use (cropland to perennial grassland) and management (stocking rate reductions and legume addition) changes to test the validity of the approach across the southwestern United States. The conversion of small grain cropland to perennial cover was simulated acceptably (<20% uncertainty) by the model for soil, climate, and management history attributes representative of 32% of land area currently in small grain production, while the simulation of small grain cropland to perennial cover + legumes was acceptable on 73% of current small grain production area. The model performed poorly on arid and semiarid rangelands for both management (reduced stocking) and restoration (legume addition) practices. Only 66% of land area currently used as rangeland had climate, soil, and management attributes that resulted in acceptable uncertainty. Based on our results, it will be difficult to credibly predict changes to soil carbon resulting from common land use and management practices, both at fine and coarse scales. To overcome these limitations, we propose an integrated system of spatially explicit direct measurement of soil carbon at locations with well-documented management histories and climatic records to better parameterize the model for rangeland applications. Further, because the drivers of soil carbon fluxes on rangelands are dominated by climate rather than management, the interface should be redesigned to simulate soil carbon changes based on ecological state rather than practice application.
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Carbon Sequestration in Agroforestry Systems
Agroforestry—the practice of growing trees and crops in interacting combinations—is recognized worldwide as an integrated approach to sustainable land-use. It is estimated to be practiced over 1 billion hectares in developing countries, and to a lesser extent in the industrialized countries. Agroforestry systems (AFSs) are believed to have a higher potential to sequester carbon (C) because of their perceived ability for greater capture and utilization of growth resources (light, nutrients, and water) than single-species crop or pasture systems. The estimates of C stored in AFSs range from 0.29 to 15.21 Mg ha− 1 yr− 1 aboveground, and 30 to 300 Mg C ha− 1 up to 1-m depth in the soil. Recent studies under various AFSs in diverse ecological conditions showed that tree-based agricultural systems, compared to treeless systems, stored more C in deeper soil layers near the tree than away from the tree; higher soil organic carbon content was associated with higher species richness and tree density; and C3 plants (trees) contributed to more C in the silt- + clay-sized (< 53 μm diameter) fractions—that constitute more stable C—than C4 plants in deeper soil profiles. The extent of C sequestered in AFSs depends to a great extent on environmental conditions and system management. Trading of the sequestered C is a viable opportunity for economic benefit to agroforestry practitioners, who are mostly resource-poor farmers in developing countries. However, more rigorous research results are required for AFSs to be used in global agendas of C sequestration.  FIND ARTICLE HERE

Mitigating the Greenhouse Gas Balance of Ruminant Production Systems Through Carbon Sequestration in Grasslands
Soil carbon sequestration (enhanced sinks) is the mechanism responsible for most of the greenhouse gas (GHG) mitigation potential in the agriculture sector. Carbon sequestration in grasslands can be determined directly by measuring changes in soil organic carbon (SOC) stocks and indirectly by measuring the net balance of C fluxes. A literature search shows that grassland C sequestration reaches on average 5 ± 30 g C/m2 per year according to inventories of SOC stocks and −231 and 77 g C/m2 per year for drained organic and mineral soils, respectively, according to C flux balance. Off-site C sequestration occurs whenever more manure C is produced by than returned to a grassland plot. The sum of on- and off-site C sequestration reaches 129, 98 and 71 g C/m2 per year for grazed, cut and mixed European grasslands on mineral soils, respectively, however with high uncertainty. A range of management practices reduce C losses and increase C sequestration: (i) avoiding soil tillage and the conversion of grasslands to arable use, (ii) moderately intensifying nutrient-poor permanent grasslands, (iii) using light grazing instead of heavy grazing, (iv) increasing the duration of grass leys; (v) converting grass leys to grass-legume mixtures or to permanent grasslands. With nine European sites, direct emissions of N2O from soil and of CH4 from enteric fermentation at grazing, expressed in CO2 equivalents, compensated 10% and 34% of the on-site grassland C sequestration, respectively. Digestion inside the barn of the harvested herbage leads to further emissions of CH4 and N2O by the production systems, which were estimated at 130 g CO2 equivalents/m2 per year. The net balance of on- and off-site C sequestration, CH4 and N2O emissions reached 38 g CO2 equivalents/m2 per year, indicating a non-significant net sink activity. This net balance was, however, negative for intensively managed cut sites indicating a source to the atmosphere. In conclusion, this review confirms that grassland C sequestration has a strong potential to partly mitigate the GHG balance of ruminant production systems. However, as soil C sequestration is both reversible and vulnerable to disturbance, biodiversity loss and climate change, CH4 and N2O emissions from the livestock sector need to be reduced and current SOC stocks preserved.  FIND ARTICLE HERE

Tillage, Cropping Sequence, and Nitrogen Fertilization Effects on Dryland Soil Carbon Dioxide Emission and Carbon Content
Management practices are needed to reduce dryland soil CO2 emissions and to increase C sequestration. We evaluated the effects of tillage and cropping sequence combinations and N fertilization on dryland crop biomass (stems + leaves) and soil surface CO2 flux and C content (0- to 120-cm depth) in a Williams loam from May to October, 2006 to 2008, in eastern Montana. Treatments were no-tilled continuous malt barley (Hordeum vulgaris L.) (NTCB), no-tilled malt barley–pea (Pisum sativum L.) (NTB-P), no-tilled malt barley–fallow (NTB-F), and conventional-tilled malt barley–fallow (CTB-F), each with 0 and 80 kg N ha–1. Measurements were made both in Phase I (malt barley in NTCB, pea in NTB-P, and fallow in NTB-F and CTB-F) and Phase II (malt barley in all sequences) of each cropping sequence in every year. Crop biomass varied among years, was greater in the barley than in the pea phase of the NTB-P treatment, and greater in NTCB and NTB-P than in NTB-F and CTB-F in 2 out of 3 yr. Similarly, biomass was greater with 80 than with 0 kg N ha–1 in 1 out of 3 yr. Soil CO2 flux increased from 8 mg C m–2 h–1 in early May to 239 mg C m–2 h–1 in mid-June as temperature increased and then declined to 3 mg C m–2 h–1 in September–October. Fluxes peaked immediately following substantial precipitation (>10 mm), especially in NTCB and NTB-P. Cumulative CO2 flux from May to October was greater in 2006 and 2007 than in 2008, greater in cropping than in fallow phases, and greater in NTCB than in NTB-F. Tillage did not influence crop biomass and CO2 flux but N fertilization had a variable effect on the flux in 2008. Similarly, soil total C content was not influenced by treatments. Annual cropping increased CO2 flux compared with crop–fallow probably by increasing crop residue returns to soils and root and rhizosphere respiration. Inclusion of peas in the rotation with malt barley in the no-till system, which have been known to reduce N fertilization rates and sustain malt barley yields, resulted in a CO2 flux similar to that in the CTB-F sequence.  FIND ARTICLE HERE

Carbon Sequestration in Agricultural Lands of The United States
In agriculture, C sequestration research has tended to focus primarily on productive cropping systems. Too few experiments have specifically addressed best management practices for improving soil C storage, and fewer yet evaluate practices to reduce emissions of non-CO2 trace gases. Research needs to be expanded to less well-defined components of US agriculture. Despite occupying 37% of total US land area, relatively little research has evaluated how different management practices may affect C sequestration in US rangelands and pasture lands. Even less is known about the management potential for mitigating GHG emissions in the US horticulture industry and for turfgrass. Organic soils and wetlands present especially complex management challenges since they involve significant emissions of more than one GHG, and practices that reduce emissions of one GHG may stimulate another. Agroforestry contributions to GHG mitigation have not been considered in national inventories. Addressing these research needs, including the challenges presented by biofuels development and climate change feedbacks on agricultural GHG emissions, will be critical for giving US agriculture the necessary tools to mitigate climate change. Continued progress on scaling and monitoring methodologies will be essential to implement regional/national analyses and assessments that climate change policies and protocols will demand.  FIND ARTICLE HERE

CO2 Capture and Separation Technologies For End-of-Pipe Applications - A Review
Carbon capture from point source emissions has been recognized as one of several strategies necessary for mitigating unfettered release of greenhouse gases (GHGs) into the atmosphere. To keep GHGs at manageable levels, large decreases in CO2 emissions through capturing and separation will be required. This article reviews the possible CO2 capture and separation technologies for end-of-pipe applications. The three main CO2 capture technologies discussed include post-combustion, pre-combustion and oxyfuel combustion techniques. Various separation techniques, such as chemical absorption, physical absorption, physical adsorption, cryogenics, membrane technology, membranes in conjunction with chemical absorption and chemical-looping combustion (CLC) are also thoroughly discussed. Future directions are suggested for application by oil and gas industry. Sequestration methods, such as geological, mineral carbonation techniques, and ocean dump are not covered in this review.  FIND ARTICLE HERE